They have been together for a decade now and their relationship is still going very well.
She has appeared in numerous international magazine covers, including Cosmopolitan, Elle, GQ, Harper's Bazaar, Marie Claire, Ocean Drive, Vogue and was the only model to appear on the cover of Glamour in the United States in 2006.
Ambrosio was a Victoria's Secret Angels from 2000 to 2017 and has modeled for brands such as Next, Armani Exchange, Christian Dior, and Ralph Lauren.
In 2012, she was ranked number six on Forbes She has since appeared in advertising campaigns for Gucci, Dolce & Gabbana, Calvin Klein, Oscar de la Renta, Christian Dior, Escada, Fendi, Giorgio Armani, Guess, Emporio Armani, Moschino, Gap, Hugo Boss, Ralph Lauren, Saks Fifth Avenue, Macy's, Revlon, and the Pirelli Calendar.
She dated Giovani Borghetti for two years when she was a teenage girl. After that, she dated Marcelo Boldrini for four years from 2001 to 2005.
She also dated Steven Allain for several months in 2005.
After that breakup, she began dating Jamie Mazur in 2007. The couple together has two children named Anja Louise Ambrosio Mazur and Noah Phoenix Ambrosio Mazur.